EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (48 parameters), and covers the Black Sea with 21504 CDI records divided per matrices: 7 biota profiles, 19677 water profiles, 1820 sediment profiles. Vertical profiles temporal range is from 1974-08-24 to 2017-10-06. Data were aggregated and quality controlled by ‘National Institute for Marine Research and Development "Grigore Antipa"’ from Romania. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names”, but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 48 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

Gridded product for visualization of Water body dissolved oxygen concentration in the Black Sea generated by DIVA 4.6.11 using all EMODNET Chemistry data from 1970 to 2014. Depth range (IODE standard depths): 0 – 250m. DIVA settings: signal-to-noise ratio and correlation length were estimated using data mean distance as a minimum (for L), and both parameters vertically filtered. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Every year of the time dimension corresponds to a 10-year centred average for each season: - winter: December - February, - spring: March - May, - summer: June - August, - autumn: September – November Units: umol/l

EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data profiles on eutrophication and acidity, and covers: the Artic Ocean, the North East Atlantic, the Greater North Sea and Celtic Seas, the Baltic Sea, the Mediterranean Sea and the Black Sea. ITS-90 water temperature and water body salinity variables have also been included ('as are') to complete the eutrophication and acidity data. If you use these variables for calculations, please refer to SeaDataNet for the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets. This European dataset is the result of the aggregation of the regional datasets concerning eutrophication and acidity present in EMODnet Chemistry. The regional datasets are automatically harvested, and the resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.13120/8xm0-5m67). Parameter names are based on P35 vocabulary, which relates to EMODnet Chemistry aggregated parameter names and is available at: https://vocab.nerc.ac.uk/search_nvs/P35/. This process were regionally performed by: 'Institute of Marine Research - Norwegian Marine Data Centre (NMD)' (Norway), 'IFREMER / IDM / SISMER - Scientific Information Systems for the SEA' (France), 'Aarhus University, Department of Bioscience, Marine Ecology Roskilde' (Denmark), 'Swedish Meteorological and Hydrological Institute (SMHI)' (Sweden), 'Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)' (Greece) and 'National Institute for Marine Research and Development 'Grigore Antipa' (Romania). When not present in original data, water body nitrate plus nitrite was calculated by summing all nitrate and nitrite parameters. The same procedure was applied for water body dissolved inorganic nitrogen (DIN), which was calculated by summing all nitrate, nitrite, and ammonium parameters. Concentrations per unit mass were converted to a unit volume using a constant density of 1.25 kg/L. The aggregated dataset can be downloaded as an ODV collection.

EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on potential hazardous substances, despite the fact that some data might not be related to pollution (e.g. collected by deep corer). Temperature, salinity and additional parameters are included when available. It covers the Black Sea. Data were harmonised and validated by the ‘National Institute for Marine Research and Development "Grigore Antipa" in Romania. The dataset contains water, sediment and biota profiles. The temporal coverage is 1974–2021 for water measurements, 1990–2022 for sediment measurements and 2008–2019 for biota measurements. Regional datasets concerning contaminants are automatically harvested and the resulting collections are harmonised and validated using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.6092/8b52e8d7-dc92-4305-9337-7634a5cae3f4). Parameter names are based on P01 vocabulary, which relates to BODC Parameter Usage Vocabulary and is available at: https://vocab.nerc.ac.uk/search_nvs/P01/. The harmonised dataset can be downloaded as as an ODV spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported into ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV). In addition, the same dataset is offered also as a txt file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms into subcomponents (substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications (e.g. LibreOffice Calc).

EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on eutrophication and acidity, and covers the Black Sea, Marmara Sea and Sea of Azov. Data were aggregated and quality controlled by 'National Institute for Marine Research and Development 'Grigore Antipa' in Romania. ITS-90 water temperature and water body salinity variables have also been included ('as are') to complete the eutrophication and acidity data. If you use these variables for calculations, please refer to SeaDataNet for the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets. Regional datasets concerning eutrophication and acidity are automatically harvested, and the resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.13120/8xm0-5m67). Parameter names are based on P35 vocabulary, which relates to EMODnet Chemistry aggregated parameter names and is available at: https://vocab.nerc.ac.uk/search_nvs/P35/. When not present in original data, water body nitrate plus nitrite was calculated by summing all nitrate and nitrite parameters. The same procedure was applied for water body dissolved inorganic nitrogen (DIN), which was calculated by summing all nitrate, nitrite, and ammonium parameters. Concentrations per unit mass were converted to a unit volume using a constant density of 1.25 kg/L. The aggregated dataset can also be downloaded as an ODV collection and spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV).

EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on potential hazardous substances, despite the fact that some data might not be related to pollution (e.g. collected by deep corer). Temperature, salinity and additional parameters are included when available. It covers the Black Sea. Data were harmonised and validated by the ‘National Institute for Marine Research and Development "Grigore Antipa" in Romania. The dataset contains water, sediment and biota profiles. The temporal coverage is 1974–2021 for water measurements, 1990–2022 for sediment measurements and 2008–2016 for biota measurements. Regional datasets concerning contaminants are automatically harvested and the resulting collections are harmonised and validated using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.6092/8b52e8d7-dc92-4305-9337-7634a5cae3f4). Parameter names are based on P01 vocabulary, which relates to BODC Parameter Usage Vocabulary and is available at: https://vocab.nerc.ac.uk/search_nvs/P01/. The harmonised dataset can be downloaded as as an ODV spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported into ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV). In addition, the same dataset is offered also as a txt file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms into subcomponents (substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications (e.g. LibreOffice Calc).

EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on eutrophication and acidity, and covers the Black Sea, Marmara Sea and Sea of Azov. Data were aggregated and quality controlled by 'National Institute for Marine Research and Development 'Grigore Antipa' in Romania. ITS-90 water temperature and water body salinity variables have also been included ('as are') to complete the eutrophication and acidity data. If you use these variables for calculations, please refer to SeaDataNet for the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets. Regional datasets concerning eutrophication and acidity are automatically harvested, and the resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.13120/8xm0-5m67). Parameter names are based on P35 vocabulary, which relates to EMODnet Chemistry aggregated parameter names and is available at: https://vocab.nerc.ac.uk/search_nvs/P35/. When not present in original data, water body nitrate plus nitrite was calculated by summing all nitrate and nitrite parameters. The same procedure was applied for water body dissolved inorganic nitrogen (DIN), which was calculated by summing all nitrate, nitrite, and ammonium parameters. Concentrations per unit mass were converted to a unit volume using a constant density of 1.25 kg/L. The aggregated dataset can also be downloaded as an ODV collection and spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV).

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants; temperature, salinity and additional sampling parameters are included when available. The spatial coverage is the Black Sea with 20693 CDI records divided per matrices: 18834 water profiles, 1852 sediment profiles and 7 biota profiles. Vertical profiles temporal range is from 1974-08-24 to 2019-12-08 for water, from 1990-07-30 to 2017-10-02 for sediment and from 2008-05-15 to 2008-08-15. Data were harmonised and quality controlled by ‘National Institute for Marine Research and Development "Grigore Antipa"’ from Romania. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: https://vocab.seadatanet.org/p01-facet-search. Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names”, but corresponding exactly to the same concepts in BODC P01 vocabulary. Detailed documentation is available at: https://doi.org/10.6092/8b52e8d7-dc92-4305-9337-7634a5cae3f4 Explore and extract data at: https://emodnet-chemistry.webodv.awi.de/contaminants%3EBlackSea The harmonised dataset can also be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as TXT file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The original datasets can be searched and downloaded from EMODnet Chemistry Chemistry CDI Data and Discovery Access Service: https://emodnet-chemistry.maris.nl/search

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, acidity and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). ITS-90 water temperature and Water body salinity variables have been also included (as-is) to complete the Eutrophication and Acidity data. If you use these variables for calculations, please refer to SeaDataNet for having the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets . This aggregated dataset contains all unrestricted EMODnet Chemistry data on Eutrophication and Acidity (14 parameters with quality flag indicators), and covers the Black Sea, Sea of Marmara and Sea of Azov with 62704 CDI records. Data were aggregated and quality controlled by 'National Institute for Marine Research and Development 'Grigore Antipa' from Romania. Regional datasets concerning eutrophication and acidity are automatically harvested and resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all Sea Regions ( https://doi.org/10.6092/9f75ad8a-ca32-4a72-bf69-167119b2cc12). When not present in original data, Water body nitrate plus nitrite was calculated by summing up the Nitrates and Nitrites. Same procedure was applied for Water body dissolved inorganic nitrogen (DIN) which was calculated by summing up the Nitrates, Nitrites and Ammonium. Parameter names are based on P35, EMODnet Chemistry aggregated parameter names vocabulary, which is available at: https://www.bodc.ac.uk/resources/vocabularies/vocabulary_search/P35/. Detailed documentation is available at: https://dx.doi.org/10.6092/4e85717a-a2c9-454d-ba0d-30b89f742713 Explore and extract data at: https://emodnet-chemistry.webodv.awi.de/eutrophication%3EBlackSea The aggregated dataset can also be downloaded as ODV collection and spreadsheet, which is composed of metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The original datasets can be searched and downloaded from EMODnet Chemistry Chemistry CDI Data and Discovery Access Service: https://emodnet-chemistry.maris.nl/search

This product displays the stations present in EMODnet validated dataset where fluoranthene levels have been measured in sediment. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0